103
|
Answers:
Reasoning
- Determine the number and relative intensities of the
signals, as well as their expected spectral position.
Number |
Groups |
Relative intensities |
Expected chemical shift(d) |
3 |
-CH3 |
3 |
0,6 ... 1,9ppm |
-CH2- |
2 |
1,9 ... 3,2ppm |
-CHO |
1 |
9,1...10ppm |
- Determine the multiplicity of the signals and the
relative intensities of the lines in a multiplet.
Group |
Coupling with |
J [Hz] |
Multiplicity |
Intensities |
CH3-CH2-CHO |
CH3-CH2-CHO |
»
7 |
3 |
3/4
: 6/4 : 3/4
|
CH3-CH2-CHO |
CH3-CH2-CHO
+
CH3-CH2-CHO |
»
7
» 2 |
4 * 2 = 8 |
see below |
CH3-CH2-CHO |
CH3-CH2-CHO |
»
2 |
2 |
1/4
: 2/4 : 1/4
|
- The splitting of the methyl proton signal is as
follows:
- These predictions are in good agreement with the
actual experimental spectrum for this molecule:
Now continue on page 102
|