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Answers:

molecule no J-coupling J-coupling
Formel 1 due to equivalency
within CH3, CH2
Formel 2
due to large separation
Schema 1
Schema 2
 
Formel due to equivalency
within CH2, CH3
due to large separation
CH3-CHBr-CO-CH2-CH3
CH3-CHBr-CO-CH2-CH3
CH3-CHBr-CO-CH2-CH3
CH3-CHBr-CO-CH2-CH3
CH3-CHBr-CO-CH2-CH3
CH3-CHBr-CO-CH2-CH3
Verbindung No J-coupling J-coupling

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