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A substance with four protons will show 4 NMR
signals if all four protons have chemical shifts,
that is when they are . That, however, is
not the case for the four thiophene protons!
You should therefore ask yourself the following question:
When do resoncance signals occur at the
same frequency?
Or to be more precise:
Under what circumstances are protons
equivalent?
When you have your answer, check here!
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